Pyridazine-oxime (pdzox)-based metal complexes were designed to coordinate in a <i>trans</i>-planar fashion around metal ions, reinforced by hydrogen bonding, as shown in Figure 1. These two features are important for the production of more predictable metallosupramolecular constructs that can be used for a variety of useful applications. Three new pyridazine-oxime complexes with Co(III), Cu(II), and Ni(II) were successfully prepared. Single crystals of these complexes were obtained, and their structures match well with the design. Substitution reactions of these metal complexes and their redox chemistry were investigated.

Synthesis, characterization, and reactivity of pyridazine-oxime metal complexes

249th National Meeting (2015)

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