Porous covalent-organic materials (COMs) are a class of porous materials with high surface area and diverse pore dimensions, topologies and chemical functionalities. Fascinated by their applications in gas storage/separation, catalysis, and electronics, more and more efforts have been devoted to this field. Different methodologies based on irreversible or reversible reactions have been adopted to construct those versatile networks. Boron chemistry, such as borate ester, boroxine, borosilicate, borazine forming reactions, has been intensively studied and applied in the synthesis of porous COMs during the past ten years. However, other than those sp2-hybridized boron formation reactions, the use of the charged, sp3-hybridized boron as the linkage to synthesize the porous networks has not been explored. In this work, we will discuss the synthesis and ion conductivities of the sp3-hybridized boron-linked network.

Studies on the synthesis and ion conductivities of sp<sup>3</sup>-hybridized boron-linked macrocycle-based covalent-organic network

249th National Meeting (2015)

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Studies on the synthesis and ion conductivities of sp3-hybridized boron-linked macrocycle-based covalent-organic network

Studies on the synthesis and ion conductivities of sp³-hybridized boron-linked macrocycle-based covalent-organic network