Pd Catalyzed C-C bond forming reactions are quite unusual in the range of mechanisms by which they occur. Particularly challenging for enantioselectivity are those C-C bond forming reactions that occur outside the coordination sphere of the metal and therefore distal to the chiral ligands attached to the metal. Creation of chiral space to impose asymmetry on such processes will be discussed.

Asymmetric C-C bond formation in outer sphere Pd catalyzed processes

249th National Meeting (2015)

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