<br/>The presence or absence of significant participation in chemical bonding by the f-orbitals in actinide materials has been a subject of debate for many years. In this talk, I will discuss a relatively direct probe of actinide involvement in bonding, ligand K-edge X-ray absorption spectroscopy. Experimental and theoretical investigations for a number of actinide complexes and solids will be presented and compared with the analogous transition metal complexes. The evidence for <i>f</i>-orbital — ligand bonding interactions, their origin, and the ramifications for actinide electronic structure will be discussed.<br/>

Covalency in the actinides probed with ligand K-edge X-ray absoprtion spectroscopy

249th National Meeting (2015)

The official archive and repository for all ACS Meetings & Expositions abstracts and select posters or presentations.