249th National Meeting (2015)

The official archive and repository for all ACS Meetings & Expositions abstracts and select posters or presentations.

American Chemical Society

Undergraduate Research at the Frontiers of Inorganic Chemistry

Utilization of sulfonamides in crystal engineering

Synthesis and characterization of five-coordinate aluminum complexes that polymerize ε-caprolactone

Modulation of tris(diphenylphosphinomethyl)phenylborate donor ability via introduction of M(CO)3 units at the boron-bound phenyl substituent

Low valent metal complexes of tris(diphenylphosphinomethyl)phenylborate

Ruthenium(II) complexes supported by electron-rich aromatic ligands for small molecule activation and catalysis

Surface chemistry of gold nanoparticles in natural environments

Theoretical investigation of trends in the HOMO to LUMO transition energies of tris(2,2’-bipyridyl)ruthenium(II) complexes containing various substituted ligands

Copper-catalyzed acyloxylation of aromatic halides

Probing the effects of environments on pKa values: Interaction of aniline with reverse micelles as monitored using by 1H NMR spectroscopy

Polymerization of ε-caprolactone by aluminum alkoxide complexes supported by tridentate ketoiminates bearing electron-withdrawing groups

Polymerization of lactide by aluminum ion pairs studied with 27Al NMR

L-Lactide and ε-caprolactone ring opening polymerization by binary catalysts systems that include bis-ligated magnesium complexes

Ambiphilic late-metal silyl and silylene complexes for cooperative activation of small molecules

Rational design of catalysts for water-gas shift reaction

Computational and synthetic study of organic-inorganic conjugate dyes for solar energy harvesting

Eggs in one basket:  Is there a role for riboflavin binding protein in copper transport and storage?

Investigating the mechanism of N-H bond activation by a sterically congested PCP-iridium complex

Spectroelectrochemical determination of the Fe(III)/Fe(II) reduction potential in recombinant, cross-linked hemoglobins

Derivatives of a metallopeptide-based mimic of nickel-containing superoxide dismutase

Twists and turns: WGS "catalysts" of Fe, Ru, and Os

Modeling the activity of the tungsten-containing nitrate reductase of Pyrobaculum aerophilium

Toward understanding the reaction mechanism of the tungstoenzyme, acetylene hydratase

Semiquinone stabilization via de novo designed protein scaffolds

Molybdate hydrolysis of phosphonothioate neurotoxin

Synthesis and photovoltaic performances of di-acetylide platinum complexes in dye-sensitized solar cells

Voltammetric studies of the Rieske protein

Multifunctional nanoclusters for biomedical applications

Optical and thermal properties of lithium-containing thiostannate with potential nonlinear optical applications

Selective hydrogenation of phenylacetylene over supported gold catalysts

Developing a method of copper(II) oxidation catalyst synthesis

Synthesis and characterization of spirocyclic monoalkylated organosilicon complexes of 1-hydroxy-2-pyridinone

Synthesis, characterization, and utility of trifluoroacetic acid and fluoroalkoxy lanthanide precursors for production of fluorinated lanthanide nanomaterials

Phenoxy-mercapto derivatives of group 4 alkoxides as core-shell precursors to group 4 ceramic-coinage metal nanomaterials

Microwave-assisted copper-catalyzed reactions of aryl halides via concurrent tandem catalysis

Tripodal carbamoylmethylphosphine oxide (CMPO) ligands for f-element chelation: Solution photophysical studies and lanthanide/actinide extraction properties

Progress toward the synthesis, characterization, and catalysis of iridium complexes containing [N,N,N]-dianionic pincer ligands

Catalytic transfer hydrogenation of aryl-alkyl ketones using Cp*Ir(III)Cl pyridinesulfonamide complexes

Interconversion of eight-coordinate, dodecahedral, rhenium(V) isomers supported by a single chelating ligand

Probing the selectivity of luminescent lanthanide complexes toward biologically relevant anions

Functional model of the first and second coordination spheres of type 2 copper nitrite reductase

Synthesis of palladium(II)-NHC compounds and their employment as cross-coupling catalysts

Catalytic transfer hydrogenation of aryl aldehydes using Cp*Ir(III) pyridinesulfonamide complexes

New phase discovered in the Cu-Ge-Te system by high-temperature solid state reaction

Lanthanides, chirality, and ionic liquids: Finding a niche with undergraduates

Metal cation detection using a novel small molecule chemosensor

Biochemical and molecular modelling studies of the interaction of organometallic ruthenium complexes containing thiosemicarbazones or curcuminoids as ligands with DNA and proteins

Methanobactin-inspired coordination chemistry with new mixed-donor ligands

Trends observed during the nickel-catalyzed dehydrogenation of ammonia-borane utilizing asymmetrical triazolylidene ligands

Precursor approach to probing host-guest binding of synthetic supercontainers

Microwave-assisted concurrent tandem catalysis (CTC) methodology for the copper-catalyzed amidation of aryl halides

Luminescence and extraction properties of novel tripodal CMPO ligands

Utilizing diphenylacetate lability in the synthesis of mixed ligand copper (II) dimers

Formation and characterization of Langmuir-Blodgett films of lipid rafts

Investigation of novel polymorphic Li2-II-IV-S4 diamond-like semiconductors utilizing synchrotron X-ray powder diffraction

Synthesis of molybdenum carbon dioxide complexes via oxidation of a carbonyl ligand

Controlling electrochemistry in the synthesis of semiconductor nanoparticles

Infrared Spectroscopic tracking of Q-state particle formation in ionomers

Si-H and Ge-H bond activation by a platinum dimer

Experimental and theoretical studies investigating the effect of solvent on 1JWH in Cp2WH2

Sulfur-hydrogen bond activation by novel iridium diphosphine complexes

IONiC VIPEr workshops at the frontiers of inorganic chemistry

Green dechlorination via functional models of cyanocobalamin

Mg deficient IONiC/VIPEr: An online community for inorganic chemists

Gold(I) complexes of 2- and 6-mercaptoazulenes: Syntheses, molecular and electronic structures, and reactivity profiles

Homoleptic transition metal complexes of the 7-azaindolide ligand featuring κ1-N1 coordination

Student explains international undergraduate research and cultural experiences

Cyclic hydroboration using azaferrocene-stabilized borenium cations

Oxidizing aldehydes with water: Catalysts for the aldehyde-water shift

Understanding functional tuning in binuclear non-heme iron enzymes through systematic variation of the G4DFsc active site

Redox-active NHC pincer ligands for Ni-catalyzed aerobic dehydrogenative C–C cross coupling

Synthesis of a series of first row transition metal complexes containing a tetradentate ligand

Creation and characterization of rubrerythrin and symerythrin model proteins

Structural and functional characterizations of 4-His/3-carboxylate G4DFsc proteins

Reactivity of bis(phosphino)ferrocenediyl containing compounds

Interactions of acrylamide with heme models

Asymmetric hydroamination with titanium and tantalum: experiment and theory

Synthesis and characterization of BIAN iron dihalide complexes

Investigation of sugar-Cu(II) and Zn(II) complexes' interactions in aqueous alkaline media

Investigating the oxidation of olefins using derivatives of the non-heme iron catalyst [Fe(BPMEN)](OTf)2]

Investigating the electronic coupling of quantum dots to crystal-bound thiols

Ligand donor effects in copper(I) and copper(II) complexes of polydentate heteroaromatic-amine ligands in the ATRP of styrene

Solvent loss and reuptake in Na[BH(C2H3N3)3] frameworks

Synthesis and reactivity of iron compounds containing acid functionalized 1,4,7-triazacyclononane ligands

Electron withdrawing capability of ligating histidine adducts influence the reduction potential of the [2Fe-2S] cluster of the Rieske protein

X-ray crystallographic analysis of reduction potential mutants of the Rieske protein from Thermus thermophilus

Development of gold(III) complexes containing ligands designed for chelation-assisted functionalization of strong, sp3-hybridized C-H bonds

Bidirectional “ping-pong” energy transfer in a Ir(III) charge transfer complex

Isolation and characterization of group 13 bis(2-(1-methylimidazolyl)methyl)amine complexes

Tuning the photophysical properties in a series of Re(I) charge transfer complexes

Ultrasmall Cu nanoparticles: A greener synthesis and catalytic studies

Undergraduate Research at the Frontiers of Inorganic Chemistry

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Utilization of sulfonamides in crystal engineering