Redox-active molecular networks assembled from polycyclic aromatic hydrocarbons are well-positioned to be integrated in electrochemical devices where charge-transport bottlenecks limit device performance. This includes their application as nanostructured redox mediators, given the exceptionally low reorganization energy required for charge transfer to (or from) them across electrolyte-current collector interfaces. I will discuss in depth how to design and apply supramolecular design principles to such nanostructured redox mediators in the context of lithium-sulfur batteries.

Supramolecular redox mediators for lithium-sulfur batteries

251st National Meeting (2016)

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