The development of new ethylene oligomerization catalysts based on first-row, transition metals has proven to be a challenging industrial feat over the last three decades. Surprisingly, very few catalytic systems have demonstrated the desired commercial viability. This owes not only to the complexity of the oligomerization chemistry, but the inherent difficulties in scaling such chemical processes and of replacing well established methods. Here, we report efforts at Chevron Phillips Chemical Co. LP in the development of next generation ethylene oligomerization catalysts. A major emphasis will focus on opportunities where new chemistry and improved catalyst design can be incorporated into process development. Furthermore, challenges of scaling up such catalytic processes will be highlighted.

Ethylene oligomerization catalyst development and process improvements

251st National Meeting (2016)

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