Graphene is praised as multifunctional wonder material and rich playground for physics. Above all, it is a two-dimensional polymer and thus a true challenge for materials synthesis. Herein we present, both, “bottom-up” precision synthesis and “top-down” fabrication protocols toward graphene. The resulting materials properties cover an enormous breadth ranging from batteries, supercapacitors, oxygen reduction catalysts, photodetectors and spin-walves to semiconductors. Another question is whether graphene holds promise for robust technologies. An attempt will be made at providing answers. Nature 2010, 466, 470; Nature Chem. 2011, 3, 61; Nature Nanotech. 2011, 6, 226; Nature Chem. 2012, 4, 699; Angew. Chem. Int. Ed. 2012, 51, 7640; Nature Commun. 2013, DOI: 10.1038/ncomms3646; Nature Commun. 2013, DOI: 10.1038/ncomms3487; Adv. Polym. Sci. 2013, 262, 61; Angew. Chem. Int. Ed. 2014, 53, 1570; J. Am. Chem. Soc. 2014, 136, 6083; Angew. Chem. Int. Ed. 2014, 53, 1538; Nature Nanotech. 2014, 9, 182; Nature Nanotech. 2014, 9, 131; Nature Chem. 2014, 6, 126; Nature Commun. 2014, DOI:10.1038/ncomms5973; Nature Nanotech. 2014, 9, 896; Nature Commun. 2014, DOI:10.1038/ncomms5253; Adv. Mater. 2015, 27, 669; ACS Nano 2015, 9, 1360; Angew. Chem. Int. Ed. 2015, 54, 2927; J. Am. Chem. Soc. 2015, 137, 6097; Nature Commun. 2015, DOI: 10.1038/ncomms8992; Nature Commun. 2015, DOI: 10.1038/ncomms8655.

Polymer chemistry of graphenes:  Synthesis, processing, applications

251st National Meeting (2016)

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