Reaction of homo propargyl alcohols with alkynes under gold catalysis gave seven-membered structure. It undergo diels-alder reaction in one pot fashion to yield subsituted tricyclic structure with excellent yield and diasteroselectivity.

Substituted tricyclic structure synthesized through gold-catalysed homopropargyl alcohol addition to alkyne followed by Diels-Alder reaction

251st National Meeting (2016)

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