We have been interested in the use of transition metal complexes as catalysts for the decomposition of formic acid and other low molecular weight carboxylic acids into gaseous products such as CO2 and H2 for their potential use as low temperature chemical gas generators. Investigation of a variety of compounds including pincer-type ligand complexes of Co, Fe, Ru and Mn have led to the discovery of catalyst systems that are effective for the decomposition of formic and oxalic acids into H2 and CO2. The synthesis and reaction chemistry of a variety of pincer-type complexes of Fe and Co will be discussed, as will the synthesis and reactivity of the unusual Mn(I) complex, [R2PN(PhSiH2)PR2]Mn(CO)2H.

Catalysts for the decomposition of formic and oxalic acid

251st National Meeting (2016)

The official archive and repository for all ACS Meetings & Expositions abstracts and select posters or presentations.