Polyoxometalate ions are an enormous class of metal-oxide clusters with extensive applications; however, the aqueous solution reaction dynamics of these ions are underexplored and many fundamental questions remain unanswered. Recently, we have been investigating the chemistry of the versatile Anderson-type polyoxometalate ions in solution. Here we will discuss the crystal structures and the reaction dynamics of these small, molybdenum-based polyoxometalates in aqueous solution.

Reaction dynamics of simple polyoxometalate ions in water

251st National Meeting (2016)

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