I will discuss our results from probing the fluorescence from single molecules of a new class of oligo(phenylenevinylene) (OPV) molecules, where four OPV “arm” molecules are linked via a single sp3 carbon center. Our results show that these so called tetrahedral molecules contain multiple chromophores with limited inter-arm coupling, but significant molecular motion about the central carbon. This motion leads to fluctuations in the both the polarizability axis of the molecule and the fluorescence intensity on the timescale of 100 ms to 10 s. The statistics of emitted photons from single tetrahedral molecules indicate that the tetrahedral molecules are able to sustain simultaneous emission from multiple arms.<br/><br/>We have shown, for the first time, direct comparisons of the detailed structures of the OPV “arm” molecules and their luminescence properties on a single molecule level and in thin films. This data originates from a combination of two powerful diagnostic tools in physical chemistry: gas-phase ion mobility and single molecule fluorescence spectroscopy. The results show that the structures observed in the gas phase are strongly correlated to the categories of molecules observed in the single molecule fluorescence measurements with nearly identical distributions for the two OPV molecules studied. These categories are determined by the number of cis vinylene linkages in the OPV structure and are shown to directly influence the fluorescence intensity, the structure of the tetrahedral molecule and the morphology of films made from these materials.

Chemical imaging at 100nm and single molecule sensitivity: Photochemistry of organic semiconductors probed by a combination of high resolution flurosecence microscopy and ion mobility mass spectrometry

251st National Meeting (2016)

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