The apparent molar volumes and isentropic compressions of aqueous solutions of tetrahydrofuran (THF), tetrahydropyran (THP), 1, 4-Dioxane (DIOX), tetrahydropyran-2-methanol (THPA), 3-hydroxytetrahydrofuran (3-OH-THF), and tetrahydrofurfuryl alcohol (THFA) were measured at 288.15 K, 298.15 K, and 313.15 K.  Results are analyzed in terms of the effects of group addition to the apparent molar volumes and isentropic compressions.  The temperature dependence of the limiting values of the apparent molar volumes and compressions, and their group contributions, are used to characterize changes in hydration.<br/>

Apparent molar volumes and isentropic compressions of cyclic ethers in aqueous solutions from 288.15 K to 313.15 K at atmospheric pressure

253rd National Meeting (2017)

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