Increased environmental and impurity restrictions on consumer products, also the desire to reduce the cost and energy requirements of chemical transformations, have established a critical need for the development of more selective and efficient catalysts. An attractive approach to addressing this need is the use of catalysts that can be altered through post-synthesis modifications. Several commonly employed methods to change catalyst reactivity post-synthesis include the manipulation of pH, photoactivation, or even changes in solvent. This talk will discuss the synthesis, characterization, and reactivity of new ligand scaffolds containing fluorescent dye fragments that are capable of manipulating metal complex reactivity through ligand-based redox events.

Influence of fluorescent dye containing ligand scaffolds on metal complex reactivity

253rd National Meeting (2017)

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