We have designed cluster molecules that are able to perform multi-electron redox chemistry through a variety of reactions. We will explore how and when redox load is distributed throughout the core, as well as counter examples when M-M bonding is limited and redox-isolated motifs arise. The electronic structure of the resultant materials will be discussed with regards to magnetic anisotropy and emergent magnetic phenomena.

Multi-electron redox chemistry: Redox load distributions in cluster cores

253rd National Meeting (2017)

The official archive and repository for all ACS Meetings & Expositions abstracts and select posters or presentations.