By relying on a variety of reversible covalent reactions that lead to readily cleaved bonds, we have prepared materials that combine the physical integrity of covalent materials and the structural dynamics of supramolecular complexes. Oximes, boronic esters, boronate esters, and Diels-Alder linkages have all been employed to prepare these responsive and dynamic materials, with particular attention having been dedicated to the preparation of hydrogels, elastomers, and nanoparticles. We seek to exploit the reversible nature of these bonds to prepare responsive and self-healing materials.

Topological transformations via dynamic-covalent chemistry

253rd National Meeting (2017)

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