Advances in metamaterials and metasurfaces have enabled unprecedented control of light-matter interactions. Metamaterial constituents support high-frequency electric and magnetic dipoles, which can be used as building blocks for new materials capable of negative refraction, electromagnetic cloaking, strong visible-frequency circular dichroism, and enhanced magnetic or chiral transitions in ions and molecules. However, most metamaterials to date have been limited to solid-state, static, narrow-band, and/or small-area structures. Here, we introduce the design, fabrication, and three-dimensional nano-optical characterization of large-area, dynamically-tunable metamaterials and gram-scale metafluids. First, we use transformation optics to design a broadband metamaterial constituent - a metallo-dielectric nanocrescent - characterized by degenerate electric and magnetic dipoles. A periodic array of nanocrescents exhibits large positive and negative refractive indices at optical frequencies that are largely insensitive to the wavelength, orientation and polarization of incident light. Then, we introduce a new tomographic technique, cathodoluminescence (CL) spectroscopic tomography, to probe light-matter interactions in individual nanocrescents with nanometer-scale resolution. Two-dimensional CL maps of the three-dimensional nanostructure are obtained at various orientations, allowing us to reconstruct the electromagnetic eigenmodes at each wavelength in three dimensions. Finally, we demonstrate the fabrication of dynamically tunable large-area metamaterials and gram-scale metafluids, using a combination of colloidal synthesis, protein-directed assembly, self-assembly, etching, and stamping. The electric and magnetic response of the bulk metamaterial and metafluid are directly probed with optical scattering and spectroscopy. Using chemical swelling, these metamaterials exhibit reversible, unity-order refractive index changes across both positive and negative indices that may provide a foundation for new adaptive optical materials in sensing, solar, stealth, and display applications.<br/>

Elastomeric and fluidic metamaterials: Towards large-area, reconfigurable metamaterials

253rd National Meeting (2017)

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