Polyoxometalates are an outstanding family of inorganic compounds well known for their huge structural diversity, interesting catalytic activities and rich electrochemistry.[1] The embedding of tetrahedral ([SO4]2–, [PO4]3–, [SiO4]4–), octahedral ([IO6]5–, [TeO6]6–) or pyramidal ([SO3]2–, [BiO3]3–) anions in the polyoxometalate structure leads to the subfamily of heteropolyoxometalates (HPOMs). In the present contribution we present our recent strategies to control, and understand the self-assembly of HPOMs by integrating a 3D printed reaction ware with mass spectrometry.

Aiming for the heteroatom control in the synthesis of polyoxometalates

253rd National Meeting (2017)

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