Technetium-99 (Tc) generated from the fission of 235U and 239Pu in high yields is one of the most difficult contaminants to be addressed at the U.S. Department of Energy (DOE) Hanford Site. Among radioactive contaminants, Tc presents a unique challenge in that it has a long half-life, exhibits diverse chemical properties and typically highly mobile in the environment leading to several uncertainties regarding treatment and disposition options. The complex behavior of Tc under storage, treatment, and immobilization conditions significantly affects its management options. The overall objective of the Technetium Management program at Pacific Northwest National Laboratory is to provide the DOE Office of Environmental Management with practical solutions to Tc needs encountered in the processing of Hanford tank waste and vadose zone remediation; and technical activities are being performed in the areas of Tc characterization, treatment, and disposition. One specific task is focused on elucidation of the identity and properties of non-pertechnetate species in the liquid Hanford tank waste. Previous analysis of the tank waste samples provided strong evidence that non-pertechnetate species can be comprised of Tc(CO)3+ complexes containing Tc in oxidation state +1. This paper describes our current results on the development of spectroscopic library of Tc(I) tricarbonyl species for their characterization and identification in the Hanford tank wastes.

Spectroscopic characterization of Tc(I) tricarbonyl species relevant to the Hanford tank waste

254th National Meeting (2017)

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