Chemically highly stable metal-organic frameworks (MOFs) incorporated with multifunctionalities are of great importance for applications under harsh environment. In this work, we presented a facile one-pot synthetic approach to incorporate multifunctionalities into stable Zr-based MOFs through mixing ligands of different geometry and connectivity. By our strategy, tetratopic tetrakis(4-carboxyphenyl)porphyrin (TCPP) ligands were successfully integrated into a series of Zr-based MOFs while maintaining the crystal structure, morphology and ultrahigh chemical stability of these parent MOFs. The amount of incorporated TCPP is controllable. This strategy offers opportunities to both tune the structure and the functionalities for better performance in various applications. We expect our strategy to provide a facile route to introduce multifunctionalities into stable Zr-MOFs for a wide variety of potential applications.

Incorporation of multifunctionalities into stable metal-organic frameworks <i>via</i> one-pot synthesis

254th National Meeting (2017)

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Incorporation of multifunctionalities into stable metal-organic frameworks via one-pot synthesis