Several (C<sub>6</sub>Me<sub>6</sub>)-supported Ru(II) complexes have been studied as catalysts for the oxidation of aldehydes to carboxylic acids, with water as the oxidant. These complexes demonstrate improved activity and selectivity over any previously reported catalytic systems. Precatalyst speciation and substrate scope will be discussed.

(Hexamethylbenzene) ruthenium catalysts for the aldehyde water shift reaction

254th National Meeting (2017)

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