Taking advantage of the newly developed “tandem active metal template” synthesis of rotaxanes using a phenanthroline strapped porphyrin, photophysical dyads and triads described in Figure 1 have been prepared with good yields. Depending on M (Zn or H2) the positioning of the dumbbell in the rotaxane could be different, as well as the nature of photoinduced process. The synthesis and morphologic characterization of the scaffolds will be presented and the photophysical data will be discussed.1

Photochemical dyads and triads built on rotaxane architectures

255th National Meeting (2018)

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