In this work we explore the synthesis of 2,6-bis(tbo)pyridine copper(I) and copper(II) complexes, and their reactions with PhINTs and its derivatives in the presence of various substrates. Competing H-atom abstraction and imido transfer pathways afford aziridines and tosyalmines. Substrate scope will be discussed and compared to related catalytic systems.<br/>

Tosylimido transfer reactions with copper complexes of 2,6-bis(tbo)pyridine

255th National Meeting (2018)

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