Palladium and platinum complexes stabilized by phosphinoferrocene ligands have been extensively studied due to their applications in homogeneous catalysis. While the majority of these reports have focused on ligands such as 1,1′-bis(diphenylphosphino)ferrocene (dppFe) and 1,1′-bis(di-isopropylphosphino)ferrocene (dipFe), much less is known about other phosphinoferrocene ligands with different electronic and steric properties. Here, we report on the reactivity and structural characterization of several new palladium and platinum carbonyl complexes supported by phosphinoferrocene ligands.

Solution and solid state structures of zerovalent palladium and platinum phosphinoferrocene complexes

255th National Meeting (2018)

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