The success of surface-bound organic reactions, e.g. taking place within a monolayer or polymer brush, hinge on a near-quantitative conversion of the reactants into the products.  This is critical, as - in contrast to solution chemistry - typically no post-reaction purification (like column chromatography or so) is feasible: what happens at the surface, stays at the surface.  Therefore there is a big drive towards the development of quantitative surface-bound reactions.  We will provide an overview of the field, and present our most recent advances in the field of SuFEx chemistry.

Surface-bound SuFEx chemistry: A fast and quantitative organic reaction

255th National Meeting (2018)

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