A nickel-iron phosphine [NiFe(CO)<sub>5</sub>(TPAP)] (where TPAP = tri(pyridylmethyl) azaphosphatrane) complex is synthesized to structurally mimic the carbon monoxide dehydrogenase (CODH) enzyme. Nuclear magnetic resonance and Infrared spectroscopy, along with X-ray crystallography were used to characterize [NiFe(CO)<sub>5</sub>(TPAP)].

Synthesis of a nickel iron phosphine complex: Structural mimic of carbon monoxide dehydrogenase (CODH)

255th National Meeting (2018)

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