More than a decade ago we synthesized the first uranyl peroxide cage clusters, and since have grown this family of nanomaterials to more than 60 published structures. Uranyl peroxide cage clusters self-assemble in water under ambient conditions, and most are highly soluble in water. This presentation will focus on recent studies that include several new structures, the overall stability of these clusters as detailed by calorimetric measurements, their solubility and properties in water, and the interchange of cluster structures in water triggered by changing pH and counter cations.<br/>

Topology, stability, solubility, and dynamics of uranyl peroxide cage clusters

255th National Meeting (2018)

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