Mononuclear and binuclear Ni complexes with triazole ligand (<i>meta</i>-xylylenebis(pyridyltriazole) (<i>m</i>-xpt) and benzylpyridyltriazole (bpt)) have been prepared in DMF solution. In each case, color changes (green to blue to pink; see figure) as a function of Ni:pyridyltriazole ratio indicated the formation of multiple species. UV-vis spectra of the solutions were analyzed to determine equilibrium constants, and some of the species were also characterized by X-ray crystallography.

Mononuclear and binuclear Ni complexes with pyridyltriazole ligands

255th National Meeting (2018)

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