We have investigated a series of dynamic building blocks based upon 1,2-oxazines. The oxazine moieties are formed via [4+2] cycloaddition reactions and are readily reversible via cycloreversion. The nature of the reversibility, stability of the constituent units, and synthetic (structurally) tunability were explored with the aim of identifying constructs that could be useful for wound healing applications, self-healing plastics, additive manufacturing, or fundamental studies in mechanochemistry.<br/>

Dynamic covalent polymers and networks based upon tunable 1,2-oxazine linkages

256th National Meeting (2018)

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