The development of aluminum complexes supporting non-innocent, redox-active ligands aims to expand the tool-box of aluminum-based chemistry through the introduction of new reactivity profiles and/or the stabilization of novel functional groups. We have been investigating the chemistry of aluminum complexes coordinated to redox-active ligands containing nitrogen heteroatoms, including diimine ligands, and will present our newest results in this area. The full characterization (small-molecule X-ray diffraction, multinuclear NMR spectroscopy, UV-vis spectroscopy, cyclic voltammetry) of complexes of various ligands will be presented and their initial reactivity profiles will be discussed.<br/> <br/>

Aluminum complexes of nitrogen-based redox-active ligands

256th National Meeting (2018)

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