We describe here our work toward developing catalytic Wittig and Pauson-Khand reactions, both enabled by the disproportionation of pnictogen oxides and carbon monoxide in the presence of a transition metal. We propose mechanisms of the different processes, supported by control experiments, in situ FTIR, and X-ray absorption spectroscopy. Application of this concept to other transformations will also be discussed.

Catalysis enabled by arsine and amine <i>N</i>-oxides and oxygen atom transfer

256th National Meeting (2018)

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Catalysis enabled by arsine and amine N-oxides and oxygen atom transfer