The construction of C-C and C-N bonds from readily available starting materials is a fundamental driving force in chemical synthesis. This presentation will discuss newly developed, general deoxygenative and desulfurative strategies to access N- and C-centered radicals, their reactivity with unsaturated systems, and mechanistic considerations of these processes.

New radical-mediated anti-Markovnikov selective alkene functionalizations

256th National Meeting (2018)

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