Metal-organic frameworks are a versatile material and have enjoyed widespread study and use as tunable scaffolds for energy storage, catalysis, and separations. Our group is interested in designing and studying hierarchically structured and responsive coordination polymers. We demonstrate the synthesis of 1- and 2-dimensional coordination polymers composed of di-Mo clusters that are also redox-active. Notably, we demonstrate the versatility of chemical vapor deposition and the unique opportunities this method presents for the preparation of layered 2-dimensional metal organic frameworks.

Gas-phase synthesis of hierarchically structured and responsive metal-organic frameworks

256th National Meeting (2018)

The official archive and repository for all ACS Meetings & Expositions abstracts and select posters or presentations.