We have previously reported the preparation of κ2 and κ3 amine bis(phenolate) complexes of Pd(II). In an effort to extend this chemistry to more abundant base metal variants, we sought to prepare manganese complexes with the same ligand class. Manganese complexes with similar ligands are often found in trimeric or multimeric forms, containing many Mn centers bridged by oxo ligands. We look to add to a small body of work that investigates the synthesis of monomeric Mn complexes using similar amine bis(phenolate) architectures with bulky substituents.

Preparation of manganese complexes of amine bis(phenolate) ligands

2019 Spring National Meeting

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