Transesterification is a powerful tool for the syntheses of novel esters from existing ester and alcohol substrates. We have discovered a series of Co and Ni(PNP) pincer compounds, that were synthesized in a straightforward three-step reaction, as highly reactive catalysts for esterification reactions. These catalysts were proven to be compatible with a multitude of ester and alcohol substrates possessing different electronic and steric properties. Lastly, we successfully employed these catalysts in the transesterification of fatty acids to synthesize complex esters commonly used in biodiesels.

Catalytic transesterification of esters with cobalt and nickel(PNP) catalysts

2019 Spring National Meeting

The official archive and repository for all ACS Meetings & Expositions abstracts and select posters or presentations.