The use of bi-functional metal organic frameworks (MOFs) to enable photoelectrocatalytic transformations is an emerging area of research. Herein, we report the synthesis of a UiO-67-type with both a photosensitizer and dark catalyst incorporated. To enable photoelectrochemical contact, the MOF is deposited on a high-surface area, nanocrystalline titanium dioxide film. Upon light excitation, the photosensitizer injects into the conduction band of TiO<sub>2</sub>. The resultant oxidized sensitizer accepts an electron from the catalyst, which then oxidizes benzyl alcohol. The ensemble is study by a combination of electrochemical and spectroscopic techniques including transient absorption spectroscopy.<br/>

Photo-electrocatalytic alcohol oxidation by a multi-component metal organic framework

2019 Spring National Meeting

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