The formation of C–C bonds via transition-metal catalyzed C-H activation has become a powerful tool for synthetic chemists. Aldehydes are common functional groups in building blocks and can undergo diverse transformations. Dynamic kinetic resolution is an emerging strategy to fully convert racemic substrates into enantioenriched products. In this poster, we describe a dynamic kinetic resolution of chiral aldehydes using transition-metal catalysis to generate C–C bonds in a stereoselective fashion.

Dynamic kinetic resolution of aldehydes for C–C bond formation

2019 Spring National Meeting

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