Developing large area electrochromic smart windows based on nanoscale materials demands that trillions of nanoparticles modulate between transparent and colored states at the same rate. However, it is unclear how nanoparticle heterogeneity contributes to variable coloration dynamics. Here we demonstrate a single nanoparticle electrochromism approach to study optical modulation rates upon lithiationof isolated, clustered, and thin film tungsten oxide nanorod electrodes. We observe a particle-dependent waiting time for coloration (from 100 ms to 10 s) due to Li-ion insertion at optically inactive surface sites. Longer nanorods achieve higher OD modulation than shorter nanorods because they develop a Li-ion gradient that increases from the nanorod ends to the middle. Interestingly, electrochromic irreversibility increases monotonically with the number of particle-particle interactions due to ion trapping at nanoparticle interfaces. These findings lead us to propose a nanostructured electrode architecture that optimizes coloration magnitude, rate, and reversibility across large area elecrochromic smart windows.

Influence of single nanoparticle electrochromic dynamics on the speed and durability of smart windows

2019 Fall National Meeting

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