Metal–organic frameworks (MOFs) are an emerging class of solid-state materials built up from metal-based nodes and organic linkers. They exhibit permanent porosity and unprecedented surface areas which can be readily tuned through coordination chemistry at the inorganic node and organic chemistry at the linkers. Importantly, the catalytically active moieties in these materials can be made in a site-isolated fashion and the cavities surrounding them can be engineered to conceptually mimic enzymes.

Single-site versus single-ion catalysts in metal–organic frameworks

2019 Fall National Meeting

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