Reduction–volatilization of arsenic from a denitration catalyst obtained from a coal-fired power plant using a gaseous reducing agent was investigated to develop a dry arsenic removal process. Methanol vapor showed higher reactivity for the reduction of the arsenic species in the catalyst than solid carbon. When the catalyst was heated under methanol atmosphere at temperatures above 350 °C, arsenic was quickly volatilized but the catalytic activity was drastically reduced. In that case, the denitration activity of the methanol-treated catalyst could be completely recovered by adding active vanadium species. It was confirmed that arsenic could be successfully removed with no decline in the catalytic activity by heating the catalyst under methanol atmosphere in the temperature range from 250 to 275 °C.

Regeneration of spent denitration catalyst of coal fired power plant

2019 Fall National Meeting

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