Carbon dioxide has received attention as an abundant, economical, and renewable C<sub>1</sub> feedstock. The catalytic conversion of carbon dioxide to chemical fuels would positively impact the global carbon dioxide balance. The heterogenization of metal complexes represents an attractive method to combine the tunability of the homogeneous systems, with the robustness and efficiency present in heterogeneous catalysts. The integration of well-known molecular catalytic units into extended frameworks will be discussed, leading to materials with improved efficiency, stability, and durability in comparison to the corresponding molecular analogues. This talk will focus on the immobilization of rhenium bipyridine moieties via covalent-organic frameworks (COFs) or via covalent attachment.

CO<sub>2</sub> reduction by immobilized rhenium bipyridine moieties

2019 Fall National Meeting

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CO2 reduction by immobilized rhenium bipyridine moieties

CO₂ reduction by immobilized rhenium bipyridine moieties