We review recent experimental results on the unimolecular chemistry of organic peroxy radicals. We describe metods for measuring the rate coefficients and products of this chemistry. A major focus of this work is to describing the rates and products of H-shift and endocylization reactions in substituted radicals, such as alcohols, peroxides derived from alkanes, aldehydes, and biogenically-derived alkenes. We illustrate how the structure of these peroxy radicals, including their stereochemistry, can inhibit or accelerate the rate of this chemistry. <br/>

Unimolecular chemistry of organic peroxy radicals in the atmosphere

2019 Fall National Meeting

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