The reactivity of heteroatom centered radicals continues to serve as inspiration for reaction development in chemical synthesis. This talk will describe recent advances using phosphorous-based reagents to generate carbon- and heteroatom-centered radicals via a sequential atom transfer approach without the need for toxic and/or precious transition metals. Efforts in methods development will be presented alongside mechanistic investigations through a combination of experimental spectroscopies and computational studies.

Radical phosphorous-mediated sequential atom-transfer approaches for chemical synthesis

ACS Spring Meeting 2021

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