The creation of sophisticated, bio-inspired cooperate active sites within metal–organic frameworks has long captured the imagination of the field. However, progress towards this goal has been stymied by limited methods for creating precise, multicomponent pores. In this presentation, I will describe a simple yet versatile templating approach to position various functional groups within MOF pores at precise relative distances and geometries. Using this templating strategy, we can selectively install pairs of carboxylic acids or amines in close proximity (&lt;7 Å). These chemically versatile functional groups can be used as synthetic handles to build up more complex cooperative active sites.

Templating cooperative active sites in metal–organic frameworks

ACS Spring Meeting 2021

The official archive and repository for all ACS Meetings & Expositions abstracts and select posters or presentations.