An introduction of low densities of functional groups in the main chain can endow polyolefins with desirable additional traits while retaining their mechanical strength and durability. For example, recyclability and environmental persistency can be improved upon and physical properties such as conductivity can be imparted. An access to such materials can be gained by a number of conceptually different approaches. Catalytic conversions of olefinic substrates are commonly a key step. This talk discusses recent findings on main-chain functionalized polyethylenes, with an emphasis on scalable synthesis methods and relevant materials properties.

Catalytic routes to main-chain functionalized polyolefins

ACS Spring Meeting 2021

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