The relationship between the interfacial rheology of nanoparticle laden air-brine interfaces and nanoparticle (NP) adsorption and interparticle interactions is not well understood, particularly as a function of the surface chemistry and salinity. Herein, a nonionic ether diol on the surface of silica NPs provides steric stabilization in bulk brine and at the air-brine interface, whereas a second smaller underlying hydrophobic ligand raises the hydrophobicity to promote NP adsorption. The level of NPs adsorption at steady state is sufficient to produce an interface with a relatively strong elastic dilational modulus E’ = dγ/dln A. However, the interface is ductile with a relatively slow change in E’ as the interfacial area is varied over a wide range during compression and expansion. In contrast, for silica NPs stabilized with only a single hydrophobic ligand, the interfaces are often more fragile and may fracture with small changes in area. The presence of concentrated divalent cations improves E’ and ductility by screening electrostatic dipolar repulsion and strengthening the attractive forces between nanoparticles. The ability to tune the interfacial rheology with NP surface chemistry is of great interest for designing more stable gas/brine foams.

Tuning surface chemistry and ionic strength to control nanoparticle adsorption and elastic dilational modulus at the air-brine interface

ACS Spring Meeting 2021

The official archive and repository for all ACS Meetings & Expositions abstracts and select posters or presentations.