High surface charge density makes it possible for charge inversion to occur in the double layer, in which cases, flow reversal appears for electroosmotic driven flow that is one of the best-known methods of fluid transport based on the electro-kinetic phenomenon. Reverse electroosmotic flow of an aqueous solution of KCl is studied using MD method. Nonequilibrium molecular dynamics simulations are carried out to investigate the effect of temperature on velocity profiles of ions and water molecules confined in charged carbon nanotubes (CNTs) with a diameter of 3.0 nm. The results demonstrate that the temperature dependence of velocity of ions and water molecules is obviously different for various distances to the tube wall. It is found that the simulated temperature has a direct effect on the ion velocity profiles, that is, as the temperature increases, the velocity of either counter-ion or co-ion in the diffuse layer increases significantly though the velocity drops sharply in the vicinity of the tube wall surface. As for water molecules, the MD simulations show plenty of velocity profiles, in which the velocity is slightly positive near the tube wall, but is negative in most of the rest region. Clearly, the temperature effect on reverse electroosmotic flow is observed, which is reflected in two aspects: the viscosity of the fluid and the distribution of ion and water molecule.


Effect of Temperature on Velocity Profiles of Ions and Water Molecules in Charged Nanotubes

Division / Sponsors: 
Heat Transfer Division (HTD), Fluids Engineering Division (FED)

Heat Transfer Summer Conference
Paper Proceedings: https://asmedigitalcollection.asme.org/HT/HT2020/volume/83709

18th International Conference on Nanochannels, Microchannels, and Minichannels
Paper Proceedings: https://asmedigitalcollection.asme.org/ICNMM/ICNMM2020/volume/83693

Fluids Engineering Division Summer Meeting
Paper Proceedings: https://asmedigitalcollection.asme.org/FEDSM/FEDSM2020/volume/83716

HT-ICNMM2020 - Virtual Conference, SHTC - Virtual Conference, FEDSM2020 - Virtual Conference

Supporting the need among researchers worldwide for additional online and multimedia content, ASME now offers the ASME Conference Video Collection. This platform will collect and provide long-term access to conference presentation videos, encompassing all technology areas within ASME's technical conference and events program. About 30,000-40,000 engineers across all mechanical engineering and related disciplines participate in ASME conferences each year. This includes authors of approximately 6,000 to 8,000 technical papers published by ASME, the majority of whom also submit video presentations for our virtual conferences. The video collection will be available as an add-on to existing product packages or as a separate subscription.