An efficient protocol for the Cα-H heteroarylation of ethers, amides and alcohols using air and light under mild conditions is described. The reaction is applicable to a wide spectrum of functional groups. The generation of C-radicals via photoinduced aerobic oxidation of ethers, amides and alcohols is the key feature of the process. Control experiments suggest a radical pathway for the reaction.

Heteroarylation of Ethers, Amides and Alcohols with Light and O2

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27th CRSI National Symposium in Chemistry

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