Radical chemistry can afford opposite or orthogonal reactivity to classic two-electron pathways. By developing radical chaperone strategies that merge open (1e-) and closed shell (2e-) processes, our talented and diverse team has harnessed this complementary reactivity and imparted new types of chemo-, regio-, and stereo- selectivity for remote, double, or reversed C-H and C-O functionalizations of alcohols, amines, and carbonyls. These radical chaperone tools are continually being developed to streamline the synthesis of complex, medicinally relevant molecules and heterocycles. This talk will highlight our newest, most exciting chemistry and the mosaic of champions behind these discoveries.

Harnessing radicals and diversity to enable unconventional reactivity

ACS Spring 2022

The official archive and repository for all ACS Meetings & Expositions abstracts and select posters or presentations.