An organocatalytic reaction was used to release the acyloxyl radicals from phenyliodine(III) dicarboxylates. After decarboxylation of the acyloxyl radicals, the resulting alkyl radicals can be used for alkylation of alkenes. The details and its mechanism will be discussed.

Organocatalyzed radical alkylation reactions using phenyliodine(III) dicarboxylates

ACS Spring 2022

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